The exhaustive list of topics in Organometallic Chemistry in which we provide Help with Homework Assignment and Help with Project is as follows:
- Ligands:
- Bonding Types, Charges, and Donor Electrons; Ligand: chelate effect and heptaciy; 18-electron rule: Usefulness and limitation
- Lewis Base Ligands: Halide donors, Oxygen ligands, Sulphur ligands, Nitrogen ligands: R3N, R2N-, RN2-; Tris(pyrazolyl)borate, A Few Biologically Important N-Ligands: imidazole, purine, porphyrine
- Carbonyls
- Phosphines
- s-bound carbon ligands: hydrides, alkyls, aryls
- p-bonded carbon ligands: alkene, alkyne, allyl, diene, arenes, arenes, metalacyles
- Metallocene and sandwich complexes
- s/p-bonded carbon ligands: carbenes, carbines
- Bimetallic complexes and Metal Clusters: Metal-metal bond in bimetallic complexes; Clusters; Isolobal analogy; Metal nanoparticles
- Elementary organometallic reactions: Ligand substitutions; Oxidative addition; Reductive elimination; Intramolecular insertions/eliminations; Nucleophillic/Electrophillic attacks on coordinated ligands.
- Homogeneous catalysis: Alkene isomerization; Hydrogenation; Hydroformylation; Monsanto acetic acid process; Alkene polymerization; Cross coupling reactions; Metathesis; C-H activation and functionalization; Oxidation of olefins; Metal Clusters and catalysis
- Physical methods in Organometallic chemistry: 1H NMR spectroscopy; 13C NMR spectroscopy; 31P NMR spectroscopy; Dynamic NMR.
- Bio-inspired Organometallic chemistry:
- Coenzyme B12, Nitrogen fixation; Nickel enzyme; Oxygenases