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The exhaustive list of topics in Organometallic Chemistry in which we provide Help with Homework Assignment and Help with Project is as follows:

  • Ligands:
  • Bonding Types, Charges, and Donor Electrons; Ligand: chelate effect and heptaciy; 18-electron rule: Usefulness and limitation
  • Lewis Base Ligands: Halide donors, Oxygen ligands, Sulphur ligands, Nitrogen ligands: R3N, R2N-, RN2-; Tris(pyrazolyl)borate, A Few Biologically Important N-Ligands: imidazole, purine, porphyrine
  • Carbonyls
  • Phosphines
  • s-bound carbon ligands: hydrides, alkyls, aryls
  • p-bonded carbon ligands: alkene, alkyne, allyl, diene, arenes, arenes, metalacyles
  • Metallocene and sandwich complexes
  • s/p-bonded carbon ligands: carbenes, carbines
  • Bimetallic complexes and Metal Clusters: Metal-metal bond in bimetallic complexes; Clusters; Isolobal analogy; Metal nanoparticles
  • Elementary organometallic reactions: Ligand substitutions; Oxidative addition; Reductive elimination; Intramolecular insertions/eliminations; Nucleophillic/Electrophillic attacks on coordinated ligands.
  • Homogeneous catalysis: Alkene isomerization; Hydrogenation; Hydroformylation; Monsanto acetic acid process; Alkene polymerization; Cross coupling reactions; Metathesis; C-H activation and functionalization; Oxidation of olefins; Metal Clusters and catalysis
  • Physical methods in Organometallic chemistry: 1H NMR spectroscopy; 13C NMR spectroscopy; 31P NMR spectroscopy; Dynamic NMR.
  • Bio-inspired Organometallic chemistry:
  • Coenzyme B12, Nitrogen fixation; Nickel enzyme; Oxygenases